Exploring the Reactivity of Na[W2(μ-Cl)3Cl4(THF)2]∙(THF)3 towards the Polymerization of Selected Cycloolefins

The bimetallic compound Na[W2(μ-Cl)3Cl4(THF)2]·(THF)3 (1, {W 3 W}6+, a′2e′4) is a highly efficient room-temperature initiator for ring opening metathesis polymerization (ROMP) of norbornene (NBE) and some of its derivatives. In most cases, addition of phenylacetylene (PA) as co-initiator improves th...

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Bibliografische Detailangaben

Hauptverfasser:	Nikolaos Saragas, Georgios Floros, Grigorios Raptopoulos, Marinos Pitsikalis, Patrina Paraskevopoulou, Konstantinos Mertis
Format:	Artigo
Sprache:	Inglês
Veröffentlicht:	MDPI AG 2015-12-01
Schriftenreihe:	Molecules
Schlagworte:	metathesis ROMP metal-metal bonds tungsten
Online-Zugang:	http://www.mdpi.com/1420-3049/20/12/19810
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