Synthesis of a novel chemotype via sequential metal-catalyzed cycloisomerizations

Sequential cycloisomerizations of diynyl o-benzaldehyde substrates to access novel polycyclic cyclopropanes are reported. The reaction sequence involves initial Cu(I)-mediated cycloisomerization/nucleophilic addition to an isochromene followed by diastereoselective Pt(II)-catalyzed enyne cycloisomer...

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Bibliografske podrobnosti

Principais autores:	Bo Leng, Stephanie Chichetti, Shun Su, Aaron B. Beeler, John A. Porco Jr.
Format:	Artigo
Jezik:	Inglês
Izdano:	Beilstein-Institut 2012-08-01
Serija:	Beilstein Journal of Organic Chemistry
Teme:	chemical diversity cycloisomerization cyclopropane diyne isochromene π-acid
Online dostop:	https://doi.org/10.3762/bjoc.8.153
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