Transition metal-free oxidative and deoxygenative C–H/C–Li cross-couplings of 2H-imidazole 1-oxides with carboranyl lithium as an efficient synthetic approach to azaheterocyclic carboranes

The direct C–H functionalization methodology has first been applied to perform transition metal-free C–H/C–Li cross-couplings of 2H-imidazole 1-oxides with carboranyllithium. This atom- and step-economical approach, based on one-pot reactions of nucleophilic substitution of hydrogen (SNH) in non-aro...

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Bibliografski detalji

Glavni autori:	Lidia A. Smyshliaeva, Mikhail V. Varaksin, Pavel A. Slepukhin, Oleg N. Chupakhin, Valery N. Charushin
Format:	Artigo
Jezik:	Inglês
Izdano:	Beilstein-Institut 2018-10-01
Serija:	Beilstein Journal of Organic Chemistry
Teme:	carboranes C–H functionalization C–H/C–Li cross-coupling 2H-imidazole 1-oxide nucleophilic substitution of hydrogen (SNH)
Online pristup:	https://doi.org/10.3762/bjoc.14.240
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