Steric Effects of Alkyl Substituents at N-Donor Bidentate Amines Direct the Nuclearity, Bonding and Bridging Modes in Isothiocyanato-Copper(II) Coordination Compounds

A series of Cu(II)-isothiocyanato coordination compounds derived from sterically hindered N-donor diamines were synthesized and characterized: catena-[Cu(Me3en)(μ-NCS)(NCS)] (1), catena-[Cu(NEt2Meen)(μ-NCS)(NCS)] (2), catena-[Cu(N,N,2,2-Me4pn)(μ-NCS)(NCS)] (3), the dimeric: [Cu2(N,N′-...

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Detalhes bibliográficos

Principais autores:	Franz A. Mautner, Roland C. Fischer, Ana Torvisco, Maher M. Henary, Andrew Milner, Hunter DeVillier, Tolga N. V. Karsili, Febee R. Louka, Salah S. Massoud
Formato:	Artigo
Idioma:	Inglês
Publicado em:	MDPI AG 2019-01-01
Colecção:	Crystals
Assuntos:	coordination compounds coordination polymers copper isothiocyanate crystal structure DFT calculations
Acesso em linha:	http://www.mdpi.com/2073-4352/9/1/38
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