Site Selectivity in Pd-Catalyzed Reactions of α-Diazo-α-(methoxycarbonyl)acetamides: Effects of Catalysts and Substrate Substitution in the Synthesis of Oxindoles and β-Lactams

The Pd-catalyzed intramolecular carbene C−H insertion of α-diazo-α-(methoxycarbonyl)acetamides to prepare oxindoles as well as β-lactams was studied. In order to identify what factors influence the selectivity of the processes, we explored how the reactions are affected by the c...

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主要な著者:	Daniel Solé, Ferran Pérez-Janer, Arianna Amenta, M.-Lluïsa Bennasar, Israel Fernández
フォーマット:	Artigo
言語:	Inglês
出版事項:	MDPI AG 2019-09-01
シリーズ:	Molecules
主題:	palladium diazo compounds carbenes oxindoles β-lactams density functional calculations
オンライン･アクセス:	https://www.mdpi.com/1420-3049/24/19/3551
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