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Nucleophilic reactivity of the gold atom in a diarylborylgold(i) complex toward polar multiple bonds
A di(o-tolyl)borylgold complex was synthesized via the metathesis reaction of a gold alkoxide with tetra(o-tolyl)diborane(4). The resulting diarylborylgold complex exhibited a Lewis acidic boron center and a characteristic visible absorption that arises from its HOMO–LUMO excitation, which is narrow...
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| Publicat a: | Chem Sci |
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| Autors principals: | , , , |
| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
The Royal Society of Chemistry
2020
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC8179162/ https://ncbi.nlm.nih.gov/pubmed/34163858 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0sc05478j |
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