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Photocontrolled Cobalt Catalysis for Selective Hydroboration of α,β‐Unsaturated Ketones

Selectivity between 1,2 and 1,4 addition of a nucleophile to an α,β‐unsaturated carbonyl compound has classically been modified by the addition of stoichiometric additives to the substrate or reagent to increase their “hard” or “soft” character. Here, we demonstrate a conceptually distinct approach...

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Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Main Authors: Beltran, Frédéric, Bergamaschi, Enrico, Funes‐Ardoiz, Ignacio, Teskey, Christopher J.
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2020
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7692884/
https://ncbi.nlm.nih.gov/pubmed/32767728
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202009893
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