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Photocontrolled Cobalt Catalysis for Selective Hydroboration of α,β‐Unsaturated Ketones

Selectivity between 1,2 and 1,4 addition of a nucleophile to an α,β‐unsaturated carbonyl compound has classically been modified by the addition of stoichiometric additives to the substrate or reagent to increase their “hard” or “soft” character. Here, we demonstrate a conceptually distinct approach...

詳細記述

保存先:
書誌詳細
出版年:Angew Chem Int Ed Engl
主要な著者: Beltran, Frédéric, Bergamaschi, Enrico, Funes‐Ardoiz, Ignacio, Teskey, Christopher J.
フォーマット: Artigo
言語:Inglês
出版事項: John Wiley and Sons Inc. 2020
主題:
オンライン・アクセス:https://ncbi.nlm.nih.gov/pmc/articles/PMC7692884/
https://ncbi.nlm.nih.gov/pubmed/32767728
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202009893
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