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Carboxylate Structural Effects on the Properties and Proton Coupled Electron Transfer Reactivity of [CuO(2)CR](2+) Cores

A series of complexes {[NBu(4)][LCu(II)(O(2)CR)] (R = −C(6)F(5), −C(6)H(4)(NO(2)), −C(6)H(5), −C(6)H (OMe), −CH(3), and −C(6)H(2)((i)Pr)(3))} were characterized (with the complex R = −C(6)H(4)(m-Cl) having been published elsewhere (Mandal et al. J. Am. Chem. Soc. 2019, 141, 17236)). All feature N,N′...

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Detalhes bibliográficos
Publicado no:Inorg Chem
Main Authors: Elwell, Courtney E., Mandal, Mukunda, Bouchey, Caitlin J., Que, Lawrence, Cramer, Christopher J., Tolman, William B.
Formato: Artigo
Idioma:Inglês
Publicado em: 2019
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7208659/
https://ncbi.nlm.nih.gov/pubmed/31710477
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.inorgchem.9b02293
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