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IR Action Spectroscopy Shows Competitive Oxazolone and Diketopiperazine Formation in Peptides Depends on Peptide Length and Identity of Terminal Residue in the Departing Fragment
The interplay between the entropically and enthalpically favored products of peptide fragmentation is probed using a combined experimental and theoretical approach. These b(2) ion products can take either an oxazolone or diketopiperazine structure. Cleavage after the second amide bond is often a fav...
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| Publicado no: | Analyst |
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| Main Authors: | , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2014
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6467643/ https://ncbi.nlm.nih.gov/pubmed/24618890 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c4an00064a |
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