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Hydrogen-Bonding-Assisted Brønsted Acid and Gold Catalysis: Access to Both (E)- and (Z)-1,2-Haloalkenes via Hydrochlorination of Haloalkynes
[Image: see text] We have developed an efficient synthesis of both (Z)- and (E)-chlorohaloalkenes via hydrochlorination of haloalkynes, based on two distinct hydrogen-bond-network-assisted catalytic systems: Brønsted acid catalysis and gold catalysis. Both systems offer high stereoselectivity, good...
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| Publicat a: | ACS Catal |
|---|---|
| Autors principals: | , , , |
| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
American
Chemical Society
2017
|
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6207084/ https://ncbi.nlm.nih.gov/pubmed/30410816 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acscatal.7b03563 |
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