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Symmetry breakdown of 4,4″-diamino-p-terphenyl on a Cu(111) surface by lattice mismatch

Site-selective functionalization of only one of two identical chemical groups within one molecule is highly challenging, which hinders the production of complex organic macromolecules. Here we demonstrate that adsorption of 4,4″-diamino-p-terphenyl on a metal surface leads to a dissymmetric binding...

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Vydáno v:Nat Commun
Hlavní autoři: Zhong, Qigang, Ebeling, Daniel, Tschakert, Jalmar, Gao, Yixuan, Bao, Deliang, Du, Shixuan, Li, Chen, Chi, Lifeng, Schirmeisen, André
Médium: Artigo
Jazyk:Inglês
Vydáno: Nature Publishing Group UK 2018
Témata:
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC6095862/
https://ncbi.nlm.nih.gov/pubmed/30115915
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/s41467-018-05719-y
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