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Triple Helicene Cage: Three‐Dimensional π‐Conjugated Chiral Cage with Six [5]Helicene Units

A three‐dimensional π‐conjugated chiral cage with six [5]helicene units (a triple helicene cage) was synthesized for the first time. Taking advantage of the Yamamoto coupling reaction, the triflate‐substituted triple [5]helicene, a strained and preorganized precursor, was dimerized to afford the tar...

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Vydáno v:ChemistryOpen
Hlavní autoři: Matsushima, Tomoya, Kikkawa, Shoko, Azumaya, Isao, Watanabe, Soichiro
Médium: Artigo
Jazyk:Inglês
Vydáno: John Wiley and Sons Inc. 2018
Témata:
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC5891663/
https://ncbi.nlm.nih.gov/pubmed/29657913
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/open.201800006
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