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Traceless Silylation of β-C(sp(3))–H Bonds of Alcohols via Perfluorinated Acetals
We report the silylation of primary C–H bonds located β to secondary and tertiary alcohols by exploiting perfluorinated esters as traceless directing groups. The conversion of a secondary or tertiary alcohol to a perfluoroalkyl ester and conversion of the ester to the corresponding silyl acetals by...
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| Publicado en: | J Am Chem Soc |
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| Autores principales: | , , |
| Formato: | Artigo |
| Lenguaje: | Inglês |
| Publicado: |
2018
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| Materias: | |
| Acceso en línea: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5809123/ https://ncbi.nlm.nih.gov/pubmed/29283571 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.7b12150 |
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