A carregar...

Desymmetrization of Diarylmethylamido Bis(phenols) through Peptide-Catalyzed Bromination: Enantiodivergence as a Consequence of a 2 amu Alteration at an Achiral Residue within the Catalyst

Diarylmethylamido bis(phenols) have been subjected to peptide-catalyzed, enantioselective bromination reactions. Desymmetrization of compounds in this class has been achieved such that enantioenriched products may be isolated with up to 97:3 er. Mechanistically, the observed enantioselectivity was s...

ver descrição completa

Na minha lista:
Detalhes bibliográficos
Publicado no:J Org Chem
Main Authors: Hurtley, Anna E., Stone, Elizabeth A., Metrano, Anthony J., Miller, Scott J.
Formato: Artigo
Idioma:Inglês
Publicado em: 2017
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5738245/
https://ncbi.nlm.nih.gov/pubmed/29020446
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.joc.7b02339
Tags: Adicionar Tag
Sem tags, seja o primeiro a adicionar uma tag!