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Constraints on the radical cation center of cytochrome c peroxidase for electron transfer from cytochrome c
The tryptophan 191 cation radical of cytochrome c peroxidase (CcP) compound I (Cpd I) mediates long-range electron transfer (ET) to cytochrome c (Cc). Here we test the effects of chemical substitution at the 191 position. CcP W191Y forms a stable tyrosyl radical on reaction with peroxide and produce...
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| Veröffentlicht in: | Biochemistry |
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| Hauptverfasser: | , , , |
| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
2016
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5689384/ https://ncbi.nlm.nih.gov/pubmed/27499202 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.biochem.6b00262 |
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