Stereospecific Allylic Functionalization: The Reactions of Allylboronate Complexes with Electrophiles

[Image: see text] Allylboronic esters react readily with carbonyls and imines (π-electrophiles), but are unreactive toward a range of other electrophiles. By addition of an aryllithium, the corresponding allylboronate complexes display enhanced nucleophilicity, enabling addition to a range of electr...

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Publicat a:J Am Chem Soc
Autors principals: García-Ruiz, Cristina, Chen, Jack L.-Y., Sandford, Christopher, Feeney, Kathryn, Lorenzo, Paula, Berionni, Guillaume, Mayr, Herbert, Aggarwal, Varinder K.
Format: Artigo
Idioma:Inglês
Publicat: American Chemical Society 2017
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC5682599/
https://ncbi.nlm.nih.gov/pubmed/29028321
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.7b10240
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