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A P-Tether-Mediated, Iterative S(N)2’-Cuprate Alkylation Strategy to Skipped Polyol Stereotetrads: Utility of an Oxidative “Function Switch” with Phosphite-Borane Tethers
The development of a P-tether-mediated, iterative S(N)2’-cuprate alkylation protocol for the formation of 1,3-skipped polyol stereotetrads is reported. This two-directional synthetic strategy builds molecular complexity from simple, readily prepared C(2)-symmetric dienediols and unites the chemistry...
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| Udgivet i: | Org Lett |
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| Main Authors: | , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2017
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5595703/ https://ncbi.nlm.nih.gov/pubmed/28471180 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.7b00852 |
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