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Anti-cooperative supramolecular polymerization: a new K (2)–K model applied to the self-assembly of perylene bisimide dye proceeding via well-defined hydrogen-bonded dimers

A perylene bisimide dye bearing amide functionalities at the imide positions derived from amino acid l-alanine and a dialkoxy-substituted benzyl amine self-assembles into tightly bound dimers by π–π-stacking and hydrogen bonding in chloroform. In less polar or unpolar solvents like toluene and methy...

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Publicat a:Chem Sci
Autors principals: Gershberg, Jana, Fennel, Franziska, Rehm, Thomas H., Lochbrunner, Stefan, Würthner, Frank
Format: Artigo
Idioma:Inglês
Publicat: Royal Society of Chemistry 2016
Matèries:
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC5582317/
https://ncbi.nlm.nih.gov/pubmed/28966774
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5sc03759j
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