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One-Pot Metal-Free Conversion of Anilines to Aryl Bromides and Iodides

A metal-free synthesis of aryl bromides and iodides from anilines via halogen abstraction from bromotrichloromethane and diiodomethane is described. This one-pot reaction affords aryl halides from the corresponding anilines in moderate to excellent yields without isolation of diazonium salts. The tr...

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Bibliographic Details
Published in:Org Lett
Main Authors: Leas, Derek A., Dong, Yuxiang, Vennerstrom, Jonathan L., Stack, Douglas E.
Format: Artigo
Language:Inglês
Published: 2017
Subjects:
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC5572204/
https://ncbi.nlm.nih.gov/pubmed/28481557
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.7b00771
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