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Correlation analysis of the rates of solvolysis of 4-bromopiperidine: a reaction following a Grob fragmentation pathway

A Grunwald-Winstein treatment of the specific rates of solvolysis of 4-bromopiperidine gives for aqueous ethanol, methanol, acetone, and dioxane a very good logarithmic correlation against the Y(Br) solvent ionizing power values with a slope (m value) of 0.46±0.02, consistent with the operation of a...

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Detalhes bibliográficos
Publicado no:Eur J Chem
Main Authors: Kevill, Dennis Neil, Ryu, Zoon Ha, D’Souza, Malcolm John
Formato: Artigo
Idioma:Inglês
Publicado em: 2017
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5515489/
https://ncbi.nlm.nih.gov/pubmed/28729923
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.5155/eurjchem.8.2.162-167.1566
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