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Isolation of a chiral anthracene cation radical: X-ray crystallography and computational interrogation of its racemization()
Chiral cation-radical salts hold significant promise as charge-transfer materials, chiroptical switches, and electron-transfer catalysts for enantioselective synthesis. Herein we demonstrate that the readily-available chiral 9,10-diphenyleanthracene derivative (i.e. (S)ANT) forms a robust cation rad...
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發表在: | Chem Commun (Camb) |
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Main Authors: | , , , |
格式: | Artigo |
語言: | Inglês |
出版: |
2017
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主題: | |
在線閱讀: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5465818/ https://ncbi.nlm.nih.gov/pubmed/28203653 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c6cc10307c |
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