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Isolation of a chiral anthracene cation radical: X-ray crystallography and computational interrogation of its racemization()

Chiral cation-radical salts hold significant promise as charge-transfer materials, chiroptical switches, and electron-transfer catalysts for enantioselective synthesis. Herein we demonstrate that the readily-available chiral 9,10-diphenyleanthracene derivative (i.e. (S)ANT) forms a robust cation rad...

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發表在:Chem Commun (Camb)
Main Authors: Ivanov, Maxim V., Thakur, Khushabu, Bhatnagar, Anshul, Rathore, Rajendra
格式: Artigo
語言:Inglês
出版: 2017
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在線閱讀:https://ncbi.nlm.nih.gov/pmc/articles/PMC5465818/
https://ncbi.nlm.nih.gov/pubmed/28203653
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c6cc10307c
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