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Isolation of a chiral anthracene cation radical: X-ray crystallography and computational interrogation of its racemization()
Chiral cation-radical salts hold significant promise as charge-transfer materials, chiroptical switches, and electron-transfer catalysts for enantioselective synthesis. Herein we demonstrate that the readily-available chiral 9,10-diphenyleanthracene derivative (i.e. (S)ANT) forms a robust cation rad...
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| Опубликовано в: : | Chem Commun (Camb) |
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| Главные авторы: | , , , |
| Формат: | Artigo |
| Язык: | Inglês |
| Опубликовано: |
2017
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| Предметы: | |
| Online-ссылка: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5465818/ https://ncbi.nlm.nih.gov/pubmed/28203653 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c6cc10307c |
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