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1-(Triethoxysilyl)buta-1,3-dienes—New Building Blocks for Stereoselective Synthesis of Unsymmetrical (E,E)-1,4-Disubstituted 1,3-dienes

A convenient methodology for the highly stereoselective synthesis of unsymmetrical (1E,3E)-1,4-disubstituted 1,3-dienes based on palladium-catalyzed Hiyama cross-coupling reaction of 1-(triethoxysilyl)-substituted buta-1,3-dienes with aryl iodides is reported.

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Detalhes bibliográficos
Publicado no:Materials (Basel)
Main Authors: Szudkowska-Frątczak, Justyna, Taczała, Mariusz, Pawluć, Piotr
Formato: Artigo
Idioma:Inglês
Publicado em: MDPI 2015
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5458880/
https://ncbi.nlm.nih.gov/pubmed/28793635
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/ma8115378
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