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Impact of backbone fluorination on nanoscale morphology and excitonic coupling in polythiophenes

Fluorination represents an important strategy in developing high-performance conjugated polymers for photovoltaic applications. Here, we use regioregular poly(3-ethylhexylthiophene) (P3EHT) and poly(3-ethylhexyl-4-fluorothiophene) (F-P3EHT) as simplified model materials, using single-molecule/aggreg...

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發表在:Proc Natl Acad Sci U S A
Main Authors: Hu, Zhongjian, Haws, Ryan T., Fei, Zhuping, Boufflet, Pierre, Heeney, Martin, Rossky, Peter J., Vanden Bout, David A.
格式: Artigo
語言:Inglês
出版: National Academy of Sciences 2017
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在線閱讀:https://ncbi.nlm.nih.gov/pmc/articles/PMC5441816/
https://ncbi.nlm.nih.gov/pubmed/28465439
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.1620722114
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