Using signal amplification by reversible exchange (SABRE) to hyperpolarise (119)Sn and (29)Si NMR nuclei

The hyperpolarisation of the (119)Sn and (29)Si nuclei in 5-(tributylstannyl)pyrimidine (A (Sn)) and 5-(trimethylsilyl)pyrimidine (B (Si)) is achieved through their reaction with [IrCl(COD)(IMes)] (1a) or [IrCl(COD)(SIMes)] (1b) and parahydrogen via the SABRE process. 1a exhibits superior activity i...

Popoln opis

Shranjeno v:
Bibliografske podrobnosti
izdano v:Chem Commun (Camb)
Main Authors: Olaru, Alexandra M., Burt, Alister, Rayner, Peter J., Hart, Sam J., Whitwood, Adrian C., Green, Gary G. R., Duckett, Simon B.
Format: Artigo
Jezik:Inglês
Izdano: Royal Society of Chemistry 2016
Teme:
Chemistry
Online dostop:https://ncbi.nlm.nih.gov/pmc/articles/PMC5436037/
https://ncbi.nlm.nih.gov/pubmed/27904890
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c6cc07109k
Oznake: Označite
Brez oznak, prvi označite!

Podobne knjige/članki