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Using signal amplification by reversible exchange (SABRE) to hyperpolarise (119)Sn and (29)Si NMR nuclei
The hyperpolarisation of the (119)Sn and (29)Si nuclei in 5-(tributylstannyl)pyrimidine (A (Sn)) and 5-(trimethylsilyl)pyrimidine (B (Si)) is achieved through their reaction with [IrCl(COD)(IMes)] (1a) or [IrCl(COD)(SIMes)] (1b) and parahydrogen via the SABRE process. 1a exhibits superior activity i...
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| Publicado no: | Chem Commun (Camb) |
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| Principais autores: | , , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Royal Society of Chemistry
2016
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5436037/ https://ncbi.nlm.nih.gov/pubmed/27904890 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c6cc07109k |
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