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A concerted two-prong approach to the in situ allosteric regulation of bifunctional catalysis

Herein, we report the reversible in situ “on–off” allosteric regulation of hydrogen-bond-donating (HBD)–Lewis base co-catalytic activity via a concerted two-prong methodology entailing cooperative acid–base chemistry and a structurally addressable coordination complex. Specifically, a heteroligated...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: McGuirk, C. Michael, Mendez-Arroyo, Jose, d'Aquino, Andrea I., Stern, Charlotte L., Liu, Yuan, Mirkin, Chad A.
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2016
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5355828/
https://ncbi.nlm.nih.gov/pubmed/28451109
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c6sc01454b
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