Distal Stereocontrol Using Guanidinylated Peptides as Multifunctional Ligands: Desymmetrization of Diarylmethanes via Ullman Cross-Coupling

We report the development of a new class of guanidine-containing peptides as multifunctional ligands for transition-metal catalysis and its application in the remote desymmetrization of diarylmethanes via copper-catalyzed Ullman cross-coupling. Through design of these peptides, high levels of enanti...

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Bibliographic Details
Published in:J Am Chem Soc
Main Authors: Kim, Byoungmoo, Chinn, Alex J., Fandrick, Daniel R., Senanayake, Chris H., Singer, Robert A., Miller, Scott J.
Format: Artigo
Language:Inglês
Published: 2016
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Article
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC5127171/
https://ncbi.nlm.nih.gov/pubmed/27254785
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.6b03444
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