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Transforming LiTMP Lithiation of Challenging Diazines through Gallium Alkyl Trans‐Metal‐Trapping
This study establishes a new trans‐metal‐trapping (TMT) procedure based on a mixture of LiTMP (the base) and tris(trimethylsilylmethyl)gallium [Ga(CH(2)SiMe(3))(3), GaR(3)] (the trap) that, operating in a tandem manner, is effective for the regioselective deprotonation of sensitive diazines in hydro...
Shranjeno v:
| izdano v: | Angew Chem Int Ed Engl |
|---|---|
| Main Authors: | , , , |
| Format: | Artigo |
| Jezik: | Inglês |
| Izdano: |
John Wiley and Sons Inc.
2016
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| Teme: | |
| Online dostop: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5113679/ https://ncbi.nlm.nih.gov/pubmed/27647741 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201607284 |
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