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How the Proximal Pocket May Influence the Enantiospecificities of Chloroperoxidase-Catalyzed Epoxidations of Olefins

Chloroperoxidase-catalyzed enantiospecific epoxidations of olefins are of significant biotechnological interest. Typical enantiomeric excesses are in the range of 66%–97% and translate into free energy differences on the order of 1 kcal/mol. These differences are generally attributed to the effect o...

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Detalhes bibliográficos
Publicado no:Int J Mol Sci
Main Authors: Morozov, Alexander N., Chatfield, David C.
Formato: Artigo
Idioma:Inglês
Publicado em: MDPI 2016
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5000694/
https://ncbi.nlm.nih.gov/pubmed/27517911
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/ijms17081297
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