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Synthesis of the C8’-epimeric thymine pyranosyl amino acid core of amipurimycin
The C8’-epimeric pyranosyl amino acid core 2 of amipurimycin was synthesized from D-glucose derived alcohol 3 in 13 steps and 14% overall yield. Thus, the Sharpless asymmetric epoxidation of allyl alcohol 7 followed by trimethyl borate mediated regio-selective oxirane ring opening with azide, afford...
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| I publikationen: | Beilstein J Org Chem |
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| Huvudupphovsmän: | , , |
| Materialtyp: | Artigo |
| Språk: | Inglês |
| Publicerad: |
Beilstein-Institut
2016
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| Ämnen: | |
| Länkar: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4979907/ https://ncbi.nlm.nih.gov/pubmed/27559421 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.12.165 |
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