Gravar-mail: Revealing the Role of the Enzyme PqqE in the Biosynthesis of the Important Bacterial Redox Cofactor Pyrroloquinoline Quinone(♦): Demonstration That the Radical S-Adenosylmethionine (SAM) Enzyme PqqE Catalyzes de Novo Carbon-Carbon Cross-linking within a Peptide Substrate PqqA in the Presence of the Peptide Chaperone PqqD