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Thermal Dehydrogenation of Base-Stabilized B(2)H(5)(+) Complexes and its Role in C–H Borylation
Thermally induced dehydrogenation of the H-bridged cation L(2)B(2)H(5)(+) (L = Lewis base) is proposed to be the key step in the intramolecular C–H borylation of tertiary amine boranes activated with catalytic amounts of strong “hydridophiles”. Loss of H(2) from L(2)B(2)H(5)(+) generates the highly...
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| Vydáno v: | Angew Chem Int Ed Engl |
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| Hlavní autor: | |
| Médium: | Artigo |
| Jazyk: | Inglês |
| Vydáno: |
2015
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| Témata: | |
| On-line přístup: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4704089/ https://ncbi.nlm.nih.gov/pubmed/26377358 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201507647 |
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