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Thermal Dehydrogenation of Base-Stabilized B(2)H(5)(+) Complexes and its Role in C–H Borylation

Thermally induced dehydrogenation of the H-bridged cation L(2)B(2)H(5)(+) (L = Lewis base) is proposed to be the key step in the intramolecular C–H borylation of tertiary amine boranes activated with catalytic amounts of strong “hydridophiles”. Loss of H(2) from L(2)B(2)H(5)(+) generates the highly...

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Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Autor principal: Prokofjevs, Aleksandrs
Formato: Artigo
Idioma:Inglês
Publicado em: 2015
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4704089/
https://ncbi.nlm.nih.gov/pubmed/26377358
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201507647
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