Styrene Aziridination by Iron(IV) Nitrides

Thermolysis of the iron(IV) nitride complex PhB(tBuIm)(3)Fe≡N with styrene leads to formation of the high spin iron(II) aziridino complex PhB(tBuIm)(3)Fe-N(CH(2)CHPh). Similar aziridination occurs with both electron-rich and electron-poor styrenes, while bulky styrenes hinder the reaction. The aziri...

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Bibliografiske detaljer
Udgivet i:Angew Chem Int Ed Engl
Main Authors: Muñoz, Salvador B., Lee, Wei-Tsung, Dickie, Diane A., Scepaniak, Jeremiah J., Subedi, Deepak, Pink, Maren, Johnson, Michael D., Smith, Jeremy M.
Format: Artigo
Sprog:Inglês
Udgivet: 2015
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Article
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC4625910/
https://ncbi.nlm.nih.gov/pubmed/26179563
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201503773
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