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Computational Insight Concerning Catalytic Decision Points of the Transition Metal Catalyzed [2 + 2 + 1] Cyclocarbonylation Reaction of Allenes

Rhodium and molybdenum catalyzed allenic [2 + 2 + 1] cycloaddition reactions give 4-alkylidene and α-alkylidene cylopentenones, respectively. The selective reaction of one double bond of the allene over another is controlled by the transition metal and not the substrate structure. Calculations were...

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Foilsithe in:Organometallics
Main Authors: Bayden, Alexander S., Brummond, Kay M., Jordan, Kenneth D.
Formáid: Artigo
Teanga:Inglês
Foilsithe: 2006
Ábhair:
Rochtain Ar Líne:https://ncbi.nlm.nih.gov/pmc/articles/PMC4441411/
https://ncbi.nlm.nih.gov/pubmed/26005240
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/om0607503
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