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Ab initio dynamics of the cytochrome P450 hydroxylation reaction
The iron(IV)-oxo porphyrin π-cation radical known as Compound I is the primary oxidant within the cytochromes P450, allowing these enzymes to affect the substrate hydroxylation. In the course of this reaction, a hydrogen atom is abstracted from the substrate to generate hydroxyiron(IV) porphyrin and...
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| Vydáno v: | J Chem Phys |
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| Hlavní autoři: | , |
| Médium: | Artigo |
| Jazyk: | Inglês |
| Vydáno: |
AIP Publishing LLC
2015
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| Témata: | |
| On-line přístup: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4367892/ https://ncbi.nlm.nih.gov/pubmed/25681906 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1063/1.4907733 |
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