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Accessing 2-(Hetero)arylmethyl-, -allyl-, and -propargyl-2,1-borazaronaphthalenes: Palladium-Catalyzed Cross-Couplings of 2-(Chloromethyl)-2,1-borazaronaphthalenes

[Image: see text] The synthesis of 2-(chloromethyl)-2,1-borazaronaphthalene has provided an opportunity to expand dramatically the functionalization of the azaborines. This azaborinyl building block can serve as the electrophile in palladium-catalyzed cross-coupling reactions to form sp(3)–sp and sp...

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Bibliographic Details
Published in:Org Lett
Main Authors: Molander, Gary A., Amani, Javad, Wisniewski, Steven R.
Format: Artigo
Language:Inglês
Published: American Chemical Society 2014
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC4251526/
https://ncbi.nlm.nih.gov/pubmed/25365512
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol5030508
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