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Catalytic, Enantioselective, Intramolecular Carbosulfenylation of Olefins. Mechanistic Aspects: A Remarkable Case of Negative Catalysis

[Image: see text] In the course of developing an enantioselective, Lewis base/Brønsted acid co-catalyzed carbosulfenylation of alkenes, a seemingly impossible conundrum arose: How could a catalyst inhibit a stoichiometric reaction? Despite the observation of very good enantioselectivities, the rate...

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Hlavní autoři: Denmark, Scott E., Chi, Hyung Min
Médium: Artigo
Jazyk:Inglês
Vydáno: American Chemical Society 2014
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC3985927/
https://ncbi.nlm.nih.gov/pubmed/24548006
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja413270h
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