Reactivity of (Dicarboxamide)M(II)-OH (M = Cu, Ni) Complexes: Reaction with Acetonitrile to Yield M(II)-Cyanomethides

The complexes (Bu(4)N)(L(Me)M(II)-OH) (L(Me) = 2,6-dimethylphenyl-substituted pyridine(dicarboxamide); M = Cu or Ni) react with CH(3)CN to yield (Bu(4)N)(L(Me)M-CH(2)CN), novel cyanomethide complexes that were fully characterized, including by X-ray crystallography. These conversions contrast with t...

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Bibliographic Details
Main Authors: Tehranchi, Jacqui, Donoghue, Patrick J., Cramer, Christopher J., Tolman, William B.
Format: Artigo
Language:Inglês
Published: 2013
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Article
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC3885180/
https://ncbi.nlm.nih.gov/pubmed/24415908
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/ejic.201300328
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