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Ruthenium catalyzed hydroaminoalkylation of isoprene via transfer hydrogenation: byproduct-free prenylation of hydantoins()
The ruthenium catalyst derived from Ru(3)(CO)(12) and triphos [Ph(2)P(CH(2)CH(2)PPh(2))(2)] promotes the direct C–C coupling of isoprene with aryl substituted hydantoins 1a–1f at the diene C4-position to furnish products of n-prenylation 2a–2f. A mechanism involving hydantoin dehydrogenation followe...
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| Hauptverfasser: | , , , , |
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| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
2013
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3730527/ https://ncbi.nlm.nih.gov/pubmed/23722271 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c3cc43463j |
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