Methyl Radicals in Oxidative Coupling of Methane Directly Confirmed by Synchrotron VUV Photoionization Mass Spectroscopy

Gas-phase methyl radicals have been long proposed as the key intermediate in catalytic oxidative coupling of methane, but the direct experimental evidence still lacks. Here, employing synchrotron VUV photoionization mass spectroscopy, we have directly observed the formation of gas-phase methyl radic...

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Bibliographic Details
Main Authors: Luo, Liangfeng, Tang, Xiaofeng, Wang, Wendong, Wang, Yu, Sun, Shaobo, Qi, Fei, Huang, Weixin
Format: Artigo
Language:Inglês
Published: Nature Publishing Group 2013
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Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC3620655/
https://ncbi.nlm.nih.gov/pubmed/23567985
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/srep01625
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