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Methyl Radicals in Oxidative Coupling of Methane Directly Confirmed by Synchrotron VUV Photoionization Mass Spectroscopy

Gas-phase methyl radicals have been long proposed as the key intermediate in catalytic oxidative coupling of methane, but the direct experimental evidence still lacks. Here, employing synchrotron VUV photoionization mass spectroscopy, we have directly observed the formation of gas-phase methyl radic...

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Main Authors: Luo, Liangfeng, Tang, Xiaofeng, Wang, Wendong, Wang, Yu, Sun, Shaobo, Qi, Fei, Huang, Weixin
Formato: Artigo
Idioma:Inglês
Publicado: Nature Publishing Group 2013
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Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC3620655/
https://ncbi.nlm.nih.gov/pubmed/23567985
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/srep01625
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