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Macrocyclization of the ATCUN Motif Controls Metal Binding and Catalysis
We report the design, synthesis and characterization of macrocyclic analogs of the amino-terminal copper and nickel binding (ATCUN) motif. These macrocycles have altered pH transitions for metal binding, and unlike linear ATCUN motifs, the optimal cyclic peptide 1 binds Cu(II) selectively over Ni(II...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2013
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3603286/ https://ncbi.nlm.nih.gov/pubmed/23421754 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic302820z |
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