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Stereoselective synthesis of trans-fused iridoid lactones and their identification in the parasitoid wasp Alloxysta victrix, Part I: Dihydronepetalactones

Starting from the enantiomers of limonene, all eight stereoisomers of trans-fused dihydronepetalactones were synthesized. Key compounds were pure stereoisomers of 1-acetoxymethyl-2-methyl-5-(2-hydroxy-1-methylethyl)-1-cyclopentene. The stereogenic center of limonene was retained at position 4a of th...

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Bibliografiska uppgifter
Huvudupphovsmän: Zimmermann, Nicole, Hilgraf, Robert, Lehmann, Lutz, Ibarra, Daniel, Francke, Wittko
Materialtyp: Artigo
Språk:Inglês
Publicerad: Beilstein-Institut 2012
Ämnen:
Länkar:https://ncbi.nlm.nih.gov/pmc/articles/PMC3458745/
https://ncbi.nlm.nih.gov/pubmed/23019455
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.8.140
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