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A Concise Total Synthesis of (±)- and (−)-Okilactomycin D
[Image: see text] The spirotetronate okilactomycin D (7) has been efficiently synthesized by a route featuring a substrate-controlled, diastereoselective (8:1) intramolecular Diels-Alder (IMDA) reaction of 11. The assigned absolute configuration of (−)-7 was confirmed.
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| Main Authors: | , |
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| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2012
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3272355/ https://ncbi.nlm.nih.gov/pubmed/22273402 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol203355g |
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