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Strained to the Limit: When a Cyclobutyl Moiety Becomes a Thermodynamic Sink in a Protolytic Ring Opening of Photogenerated Oxetanes

[Image: see text] Strained polycyclic oxetanes generated photochemically from the Diels-Alder adducts of cyclic dienes and enones undergo deep skeletal rearrangements under protolytic ring-opening conditions offering expeditious access to chlorohydrins and other products of unique skeletal topology.

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書誌詳細
主要な著者: Valiulin, Roman A., Arisco, Teresa M., Kutateladze, Andrei G.
フォーマット: Artigo
言語:Inglês
出版事項: 2010
主題:
オンライン・アクセス:https://ncbi.nlm.nih.gov/pmc/articles/PMC2912957/
https://ncbi.nlm.nih.gov/pubmed/20608636
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol101297b
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