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Control of Reduction Thermodynamics in [2Fe-2S] Ferredoxins. Entropy-Enthalpy Compensation and the Influence of Surface Mutations

The reaction thermodynamics for the one-electron reduction of the [2Fe-2S] cluster of both human ferredoxin and various surface point mutants, in which each of the negatively charged residues Asp72, Glu73, Asp76, and Asp79 were converted to Ala, have been determined by variable temperature spectroel...

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Detalhes bibliográficos
Main Authors: Bellei, Marzia, Battistuzzi, Gianantonio, Wu, Shu-pao, Mansy, Sheref S., Cowan, James A., Sola, Marco
Formato: Artigo
Idioma:Inglês
Publicado em: 2010
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Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2891050/
https://ncbi.nlm.nih.gov/pubmed/20362339
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.jinorgbio.2010.03.001
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