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An Investigation of the Catalytic Mechanism of S-adenosylmethionine Synthetase by QM/MM Calculations(†)
Catalysis by S-adenosylmethionine synthetase has been investigated by quantum mechanical/molecular mechanical calculations, exploiting structures of the active crystalline enzyme. The transition state energy of +19.1 kcal/mol computed for a nucleophilic attack of the methionyl sulfur on carbon-5′ of...
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| Autors principals: | , , , |
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| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
2009
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2788016/ https://ncbi.nlm.nih.gov/pubmed/19699176 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.abb.2009.08.010 |
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